CaxWO3bronze synthesized under high pressure

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β-CaB4O7: A New Polymorph Synthesized under High-Pressure/High-Temperature Conditions

A new oxoborate β -CaB4O7 has been synthesized under high-pressure/high-temperature conditions from calcium oxide and boron oxide with a Walker-type multianvil apparatus at 7.7 GPa and 1100 ◦C. Single crystal X-ray structure determination of β -CaB4O7 revealed: Pmn21, a = 1058.4(1), b = 436.9(1), c = 419.4(1) pm, Z = 2, R1 = 0.0305, wR2 = 0.0587 (all data). The compound is isotypic to the known...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography

سال: 1996

ISSN: 0108-7673

DOI: 10.1107/s010876739608614x